Experimental measurement and prediction of ionic liquid ionisation energies
نویسندگان
چکیده
Non-resonant and resonant photoelectron spectroscopy was used to measure electronic structure descriptors for 60 ionic liquids, allowing the development of design rules predict a further 516 liquids.
منابع مشابه
simulation and experimental studies for prediction mineral scale formation in oil field during mixing of injection and formation water
abstract: mineral scaling in oil and gas production equipment is one of the most important problem that occurs while water injection and it has been recognized to be a major operational problem. the incompatibility between injected and formation waters may result in inorganic scale precipitation in the equipment and reservoir and then reduction of oil production rate and water injection rate. ...
Interaction and micellar behavior of aqueous mixtures of surface active ionic liquid and cationic surfactant: experimental and theoretical studies
The interaction between an ionic liquid (1-dodecyl-3-methylimidazolium bromide or IL) and cationic surfactant (dodecyltrimethylammonium bromide (DTAB)) in aqueous solution has been investigated at various mole fractions and temperature 30 ˚C using experimental and theoretical methods. The critical micelle concentration (CMC) of pure components and their binary mixtures, mixed micellar compositi...
متن کاملCharging of ionic liquid surfaces under X-ray irradiation: the measurement of absolute binding energies by XPS.
Ionic liquid surfaces can become electrically charged during X-ray photoelectron spectroscopy experiments, due to the flux of photoelectrons leaving the surface. This causes a shift in the measured binding energies of X-ray photoelectron peaks that depends on the magnitude of the surface charging. Consequently, a charge correction method is required for ionic liquids. Here we demonstrate the na...
متن کاملDirect UV-spectroscopic measurement of selected ionic-liquid vapors.
The hallmark of ionic liquids lies in their negligible vapor pressure. This ultralow vapor pressure makes it difficult to conduct the direct spectroscopic measurement of ionic-liquid vapors. In fact, there have been no electronic spectroscopic data currently available for ionic-liquid vapors. This deficiency significantly hampers the fundamental understanding of the unique molecular structures ...
متن کاملTheoretical Prediction of Ionisation Properties of Proteins
........................................................................................................................... ii Main references ..............................................................................................................iii Abbreviations ................................................................................................................. iv
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical Chemistry Chemical Physics
سال: 2021
ISSN: ['1463-9076', '1463-9084']
DOI: https://doi.org/10.1039/d1cp02441h